Nuclear Physics
Table of Contents
1. Radioactivity
1.1. Conservation Laws
- Conservation of energy and momentum
- Conservation of charge
- Conservation of
- Conservation of the number of nucleons. This is not universal.
1.2. Activity
Activity \(\alpha\) the average number of decays per unit time. See units of activity. As decay is spontaneous process, \[ \alpha(t) = \lambda N(t) \] where \(\lambda\) is the decay constant, and \(N(t)\) is the number of atoms.
With only a single decay path is available, the number of atoms decay exponentially: \[ \dv{N}{t} = -\lambda N(t) \implies N(t) = N_0 e^{-\lambda t}. \]
The half-life is then directly related to the decay constant \(T_{1/2} = \ln 2/\lambda\). and decay factor is the fraction of atoms that remains, namely \(e^{-\lambda t}\).
1.2.1. Specific Activity
Specific activity is the activity per unit mass.
Carrier-free specific activity (CFSA) is the maximum possible specific activity when there is no other carrier, the stable isotopes of the radionuclides, present in the sample.
1.3. Q-value
The difference in the rest energy before and after the decay is called the Q-value.
Useful to know that \[ c^2 \simeq 931 \text{ MeV/amu}. \]
1.4. Binding Energy
Binding energy of a nucleus \(a\) is given by \[ \mathrm{BE} := Zm_p + Nm_n - m_a. \]
The binding energy per nucleon is highest at Fe.
1.5. Separation Energy
Separation energy is the binding energy of a particular nucleon. It is measured similar to ionization energy. For the least bound neutron, sometimes called the last neutron is \[ E_S = [m_n + m(^{A-1}Z) - m(^AZ)]c^2 \]
1.6. Alpha Decay
It is a probabilistic process of tunneling out of the potential well of the strong force.
The element above the iron is technically unstable, but the energy of the alpha particle within the neucleus is so small that the probalitity of tunneling is minute compared to the highly unstable ones.
1.7. Beta Decay
Beta decay occurs in the direction that stabilizes the nucleus. According to shell model, excess nucleon converts into the other and stabilizes the overall configuration.
2. Nuclear Models
The energy states of protons and neutrons are quantized
2.1. Segre Chart
- Chart of the Nuclides
The matrix with proton number \(Z\) on one axis (usually y-axis) and neutron number on the othe axis.
2.2. Shell Model
Separate shells for protons and neutrons, just like the electron shells in an atom.
This causes the stability of nucleus when there are roughly the same of neutrons and protons. For heavy nuclei, more nuetron is needed in order to overcome the coulombic repulsion between protons.
Spin-orbit coupling is much more significant in nucleus on the order of 1 to 10 MeV. The nucleons have strong tendency to pair up with opposite total angular momentum nucleons due to the strong nuclear interaction. For example in \(j = 5/2\) shell, 5/2 pairs with -5/2, 3/2 pairs with -3/2, 1/2 pairs with -1/2.
There only exists four stable odd-odd nuclides \(\rm ^2_1H, ^6_3Li, ^{10}_5B, ^{14}_8N\), among 165 stable nuclides, due to the strong tendency of nucleons to pair up.
2.3. Liquid Drop Model
The analogue to a liguid droplet.
This model gives the semi-empirical mass equation: \[ m = m_nN + m_pZ -\alpha A + \beta A^{2/3} + \gamma \frac{Z^2}{A^{1/3}} + \zeta \frac{(A - 2Z)^2}{A} + \delta \] where the third term is accounting for strong force, fourth term is for surface tension, fifth term is for coulombic force, sixth term is for the unstability due to imbalanced number of protons and nuetons, and seventh term is pairing term, it is positive if both are odd, negative if both are even, zero otherwise.
The coefficients are fitted to be:
| mₙ | 939.573 MeV |
| mₚ | 938.280 MeV |
| α | 15.56 MeV |
| β | 17.23 MeV |
| γ | 0.697 MeV |
| ζ | 23.285 MeV |
| δ | 12.0 MeV |
3. Nuclear Magnetic Resonance
- NMR
According to shell model, the unpaired nucleons are responsible for the magnetic moment of the nucleus.
Some nuclei have the ability to absorb radiofrequency energy and emit it, under a magnetic field.
3.1. Process
- Magnetic field aligns nuclei.
- RF pulse tips nuclei
- Nuclei precess giving off RF signal (NMR)
- The time for the signal to die off is \(T_2\), so this process is called \(T_2\) relaxation
- Nuclei realign with the field
- \(T_1\) relaxation
3.2. Magnetic Moment
\[ \vec{\mu}=\hbar\vec{S}\gamma \] where \(\vec{\mu}\) is the magnetic moment, \(\vec{S}\) is the spin and \(\gamma\) is the gyromagnetic ratio.
3.3. Larmor Frequency
- Obtained by solving the Bloch equation.
\[ \omega = -\gamma B \] where \(\omega\) is the angular frequency at which angular momentum vector precesses, \(\gamma\) is the gyromagnetic ratio and \(B\) is the magnitude of magnetic field.
3.4. Relaxation
3.4.1. T₂ Relaxation
The signal undergoes free induction decay (FID) which is the result of nuclei becoming incoherent due to the interactions within them. \[ M_r(t)=M_0e^{-t/T_2} \] in rotating frame.
3.4.2. T₁ Relaxation
- As the nuclei realign, magnetization increases
- \[ M_z(t)=M_0(1-e^{-t/T_1}) \] in rotating frame.
3.5. Polarization
\[ P=\frac{N_{\uparrow}-N_{\downarrow}}{N_\uparrow+N_\downarrow} \] \[ N_i=N_{\rm total}\frac{e^{-E_i/kT}}{\sum_j e^{-E_j/kT}} \] \[ E_\downarrow = \hbar\omega/2\quad E_\uparrow = -\hbar\omega/2 \]
With a small angle approximation, \[ P \approx \frac{\hbar\gamma B}{2kT} \]
The signal strength in thermal equilibrium is \[ S=\frac{N\gamma^3\hbar^2B_0^2}{2kT} \]
The signal \(S(t)\) produced by precesssing nuclei is \[ S(t)=NP\sin(\theta)\gamma B\cos(\omega t)e^{-t/T_2} \] where \(N\) is the total number of nuclei, \(P\) is the polarization, \(\theta\) is the flip angle.
3.6. Boltzmann Magnetization
- Nuclear magnetization in thermal equilibrium.
\[ M_0=\sum \vec{\mu}=\mu N P\equiv \chi_0 B_0 \] where \(\chi_0\) is the magnetic nuclear susceptability.
3.6.1. Curie Law
- After Pierre Curie, the husband of Marie Curie.
3.7. Inhomogeneous Magnetic Field
A small inhomogeneity in the magnetic field can leads to a rapid decay.
\[ M(t)=\mu\int f(\omega) e^{-i\omega t} d\omega \] where \(f(\omega)\) is the Lorentzian distribution that represent \(\omega\) frequency distribution.
Each nucleus has \(\omega=\omega_{\text{Larmor}}+\Delta \omega_{T_2 \text{ decay}} + \Delta\omega_{B_0 \text{ inhomogeneity}}\).
Experimental decay rate \(R^*\) is given by \[ R^*=\frac{1}{T_2}+\gamma \Delta B \]
3.8. Spin Echo
Transmit another pulse that flips the spins 180 degrees. The spin echo is observed after the same amount of time as the time from the time of aligning to the pulse.
4. Wigner Surmise
The probability distribution of the spaces between spectra of nuclei of heavy atoms. The random matrix theory was found to be useful here.